🇵🇱 GŁÓWNY INSPEKTORAT OCHRONY ŚRODOWISKA PL

PCA AB 322 • Warszawa, Poland • 169 methods

Water & wastewaterEnvironmentMaterials & polymersElectronics & EMC

GŁÓWNY INSPEKTORAT OCHRONY ŚRODOWISKA is a laboratory accredited by PCA under number AB 322 (Warszawa, Poland). Its accreditation scope covers 169 test methods in the following areas: Water & wastewater, Environment, Materials & polymers, Electronics & EMC. Test objects include: Water, Wastewater, Waste gases, Sewage sludge, Soil. Most frequently used techniques: Spectrophotometric method, Gravimetric method, Titrimetric method.

At a glance

  • Accreditation number: PCA AB 322
  • Methods in scope: 169
  • Types of test objects: 19
  • Techniques used: 33
  • City: Warszawa, Poland
Accreditation number
AB 322
Accreditation body
PCA
Address
ul. Chmielna 132/134, 00-805 Warszawa, CENTRALNE LABORATORIUM BADAWCZE, ODDZIAŁ W WARSZAWIE, ul. Bartycka 110 A
City
Warszawa, Poland

What this laboratory tests (19)

Analytical techniques used (33)

Accreditation scope — test methods (169)

No. Test object Methodology / Parameters Technique Reference document
Test methods
1 Wastewater Sampling for chemical, biological and physical testing Temperature of wastewater / of the sample taken
wastewater Range (1,0 – 50) oC
PN-ISO 5667-10:2021-11 | PN-77/C-04584
2 Groundwater Sampling for chemical and physical testing Temperature of water/of the water sample taken
Range (1,0 – 50) oC
PN-ISO 5667-11:2017-10 | PN-77/C-04584
3 Water Sampling for chemical and physical testing Temperature of water / of the water sample taken
Range (1,0 – 50) oC
PN-EN ISO 5667-6:2016-12 z wył. pkt 7.5, 7.6 | PN-77/C-04584
4 Water Dissolved oxygen concentration
Range (0,5 – 15) mg/dm3
Electrochemical method PN-EN ISO 5814:2013
5 Water Electrical conductivity at 20 oC
Range (100 – 20000) μS/cm
Conductometric method PN-EN 27888:1999
6 Soil Sampling for chemical and physical testing PN-ISO 10381-4:2007 | PN-ISO 10381-5:2009
7 Water, Wastewater pH
Range 2,0 – 12,0
Potentiometric method PN-EN ISO 10523:2012
8 Waste Intervention testing (according to programme DAB-11) PB-11/CLB wydanie 1 z dnia 25.09.2023r.
9 Sewage sludge Sampling for chemical, physical and biological testing PN-EN ISO 5667-13:2011
10 Waste gases Sampling for determination of the dust fraction PN-Z-04030-7:1994 | PN-EN 13284-1:2018-02
11 Waste gases Emission of dust fractions ( calculated) PN-Z-04030-7:1994 | PN-EN 13284-1:2018-02
12 Waste gases Dust sampling for determination of heavy metals in dust PN-Z-04030-7:1994
13 Waste gases Emission of heavy metals in dust (calculated) PN-Z-04030-7:1994
14 Dust samples Share of dust fractions (particle size distribution) including PM2,5 and PM10
Range (0,1 – 100) μm Range (0 – 100) %
Laser diffraction method with liquid dispersion ISO 13320:2020
15 General environment – noise from installations, equipment and industrial plants A-weighted equivalent sound pressure level
Range (24 – 135) dB
Direct measurement method Załącznik nr 7 do Rozporządzenia Ministra Klimatu i Środowiska z dnia 07.09.2021 r. (t. j. Dz.U. z 2023 r., poz. 1706) z wyłączeniem punktu F
16 General environment – noise from installations, equipment and industrial plants A-weighted equivalent sound pressure level for the reference time T expressed by the indicators LAeqD and LAeqN (calculated) Załącznik nr 7 do Rozporządzenia Ministra Klimatu i Środowiska z dnia 07.09.2021 r. (t. j. Dz.U. z 2023 r., poz. 1706) z wyłączeniem punktu F
17 General environment – impulse noise from installations, equipment and industrial plants A-weighted equivalent sound pressure level
Range (24 – 135) dB
Direct measurement method Załącznik nr 8 do Rozporządzenia Ministra Klimatu i Środowiska z dnia 07.09.2021 r. (t. j. Dz.U. z 2023 r., poz. 1706)
18 General environment – impulse noise from installations, equipment and industrial plants A-weighted equivalent sound pressure level for the reference time T expressed by the indicators LAeqD and LAeqN (calculated) Załącznik nr 8 do Rozporządzenia Ministra Klimatu i Środowiska z dnia 07.09.2021 r. (t. j. Dz.U. z 2023 r., poz. 1706)
19 General environment – noise from roads, railway lines, tram lines A-weighted equivalent sound level A-weighted sound exposure level
Range (24 – 135) dB
Direct measurement method Załącznik nr 3 do Rozporządzenia Ministra Środowiska z dnia 16.06.2011 r. (Dz. U. 2011 nr 140 poz. 824 i nr 288, poz. 1697) z wyłączeniem punktu H
20 General environment – noise from roads, railway lines, tram lines A-weighted equivalent sound pressure level for the reference time T expressed by the indicators LAeqD and LAeqN (calculated) Załącznik nr 3 do Rozporządzenia Ministra Środowiska z dnia 16.06.2011 r. (Dz. U. 2011 nr 140 poz. 824 i nr 288, poz. 1697) z wyłączeniem punktu H
21 General environment – noise from airports A-weighted sound exposure level A-weighted equivalent sound level
Range (24 – 130) dB
Direct measurement method Załącznik nr 2 do Rozporządzenia Ministra Środowiska z dnia 16.06.2011 r. (Dz. U. 2011 nr 140, poz.824) z wyłączeniem punktu H
22 General environment – noise from airports A-weighted equivalent sound pressure level for the reference time T expressed by the indicators LAeqD and LAeqN (calculated) Załącznik nr 2 do Rozporządzenia Ministra Środowiska z dnia 16.06.2011 r. (Dz. U. 2011 nr 140, poz.824) z wyłączeniem punktu H
23 Environment – electromagnetic field in the vicinity of electric power substations and power lines Electric field strength:
in the frequency range 50 Hz Range (1,0 – 20000) V/m
Direct measurement method Załącznik do Rozporządzenia Ministra Klimatu z dnia 17.02.2020 r. (Dz.U. 2022 poz. 2630)
24 Environment – electromagnetic field in the vicinity of electric power substations and power lines Magnetic flux density:
in the frequency range 50 Hz Range 1μT – 10 mT
Direct measurement method Załącznik do Rozporządzenia Ministra Klimatu z dnia 17.02.2020 r. (Dz.U. 2022 poz. 2630)
25 Environment – electromagnetic field in the vicinity of electric power substations and power lines Magnetic field strength:
in the frequency range 50 Hz (calculated)
Załącznik do Rozporządzenia Ministra Klimatu z dnia 17.02.2020 r. (Dz.U. 2022 poz. 2630)
26 Environment – electromagnetic field in the vicinity of radiocommunication installations (broadband measurements) Electric field strength:
in the frequency range: from 10 MHz do 40 GHz Range (0,8 – 300) V/m
Direct measurement method Załącznik do Rozporządzenia Ministra Klimatu z dnia 17.02.2020 r. (Dz.U. 2022 poz. 2630)
27 Environment – electromagnetic field in the vicinity of radiocommunication installations (broadband measurements) Magnetic field strength:
in the frequency range from 10 MHz do 40 GHz (calculated)
Punkt 3 załącznika do Rozporządzenia Ministra Klimatu dnia 17.02.2020 r. (Dz.U. 2022 poz. 2630)
28 Waste gases Gas volume flow rate for dynamic pressures >10Pa
Gas velocity Range (1,0 – 6) m/s
Stagnation pressure method; Anemometric method PN-Z-04030-7:1994
29 Waste gases Sampling for determination of dust concentration PN-Z-04030-7:1994
30 Waste gases Dust concentration
Range (0,001 – 100) g/m3
Gravimetric method PN-Z-04030-7:1994
31 Waste gases Dust emission (calculated) PN-Z-04030-7:1994
32 Waste gases Gas velocity and volume flow for differential pressures >5 Pa Differential pressure measurement method PN-EN ISO 16911-1:2013-07 CEN/TR 17078:2017-03
33 Waste gases Gas velocity
Range (1,0 – 6) m/s
Anemometric method PN-EN ISO 16911-1:2013-07 CEN/TR 17078:2017-03
34 Waste gases Sampling for determination of dust concentration PN-EN 13284-1:2018-02
35 Waste gases Dust concentration
Range (1,0 – 50) mg/m3
Gravimetric method PN-EN 13284-1:2018-02
36 Waste gases Dust emission (calculated) PN-EN 13284-1:2018-02
37 Waste gases Carbon monoxide concentration
CO (5 – 2900) mg/m3
Non-dispersive infrared spectrometry (NDIR) PN-ISO 10396:2001 | PN-EN 15058:2017-04
38 Waste gases Carbon monoxide emission (calculated) PN-ISO 10396:2001 | PN-EN 15058:2017-04
39 Waste gases Water vapour concentration (H2O)
Range (4,0 - 40,0) % Water vapour content Range (29 -250 ) g/m3
Condensation-adsorption method PN-EN 14790:2017-04
40 Waste gases Concentration of: sulphur dioxide, carbon dioxide
SO2 (9 – 3000) mg/m3 CO2 (0,1 – 21) %
Non-dispersive infrared spectrometry (NDIR) PN-ISO 10396:2001
41 Waste gases Emission: SO2, CO2 (calculated) PN-ISO 10396:2001
42 Waste gases Mass concentration of total organic carbon (TVOC)
Range (2 – 500) mg/m3
Continuous measurement method with flame ionization detection FID PN-EN 12619:2013
43 Waste gases Emission of total organic carbon (TVOC) (calculated) PN-EN 12619:2013
44 Waste gases Oxygen concentration
Range (0,1 – 21,0) %
Paramagnetic method PN-ISO 10396:2001 | PN-EN 14789:2017-04
45 Waste gases Concentration of nitrogen monoxide, nitrogen oxides
NO (2,0 – 1500) mg/m3 NOx (3,0 – 2100) mg/m3
Chemiluminescence method PN-ISO 10396:2001 | PN-EN 14792:2017-04
46 Waste gases Emission: NO, NOx (NO and NO2 calculated as NO2) (calculated) PN-ISO 10396:2001 | PN-EN 14792:2017-04
47 Waste gases Sampling for the determination of concentrations of individual gaseous organic compounds Aspiration method using activated carbon PN-EN 13649:2005
48 Waste gases Emission of individual gaseous organic compounds (calculated) PN-EN 13649:2005
49 Waste gases Sampling for determination of concentrations of organic compounds Aspiration method using activated carbon and silica gel PN-Z-04008-4:1999
50 Waste gases Emission of organic compounds (calculated) PN-Z-04008-4:1999
51 Water, Wastewater Permanganate index
Range (0,5 – 50) mg/dm3 O2
Titrimetric method PN-EN ISO 8467:2001
52 Water, Wastewater Chemical oxygen demand
COD-Cr Range (10,0 – 4000) mg/dm3 O2
Spectrophotometric method PN-ISO 15705:2005
53 Water, Wastewater Biochemical oxygen demand
BOD5 Range (0,5 – 6,0) mg/dm3 O2
Electrochemical method PN-EN 1899-2:2002
54 Water, Wastewater Biochemical oxygen demand
BOD5 Range (1,0 – 6000) mg/dm3 O2
Electrochemical method PN-EN ISO 5815-1:2019-12
55 Water, Wastewater Ammonium nitrogen concentration
Range (1,00 – 100) mg/dm3
Titrimetric method PN-ISO 5664:2002
56 Water, Wastewater Nitrite nitrogen concentration
Range (0,010 – 10) mg/dm3
Spectrophotometric method PN-EN 26777:1999
57 Water, Wastewater Kjeldahl nitrogen concentration
Range (0,50 – 500) mg/dm3
Titrimetric method PN-EN 25663:2001
58 Water, Wastewater Total nitrogen concentration (calculated) PB-049/WA wydanie 3 z dnia 15.07.2019 r.
59 Water, Wastewater Total dissolved solids (TDS)
Range (50,0 – 2000) mg/dm3
Gravimetric method PN-EN 15216:2022-03
60 Water, Wastewater Total suspended solids (TSS)
Range (2,0 – 2000) mg/dm3
Gravimetric method PN-EN 872:2007+Ap1:2007
61 Water, Wastewater Total hardness (calculated) PB-060/WA wydanie 2 z dnia 15.07.2019 r.
62 Water, Wastewater Total phosphorus concentration
Range (0,040 – 56,0) mg/dm3
Spectrophotometric method PN-EN ISO 6878:2006 +Ap1:2010+Ap2:2010
63 Water, Wastewater Concentration of substances extractable with petroleum ether
Range (0,5 – 2000) mg/dm3
Gravimetric method PN-86/C-04573.01
64 Water, Wastewater Total organic carbon concentration
Range (2,00 – 500) mg/dm3
Spectrometry method in the infrared range (IR) PN-EN 1484:1999
65 Water, Wastewater Mineral oil index
Range (0,1 – 50) mg/dm3
Gas chromatography with flame ionization detection (GC-FID) PN-EN ISO 9377-2:2003
66 Water, Wastewater Ammonium nitrogen concentration
Range (0,05 – 5,0) mg/dm3
Continuous flow analysis (CFA) with spectrophotometric detection PN-EN ISO 11732:2007 z wyłączeniem punktu 3
67 Water, Wastewater Nitrate nitrogen concentration
Range (0,10 – 50) mg/dm3
Continuous flow analysis (CFA) with spectrophotometric detection PN-EN ISO 13395:2001
68 Water, Wastewater Nitrite nitrogen concentration
Range (0,003 – 1,0) mg/dm3
Continuous flow analysis (CFA) with spectrophotometric detection PN-EN ISO 13395:2001
69 Water, Wastewater Total phosphorus concentration
Range (0,050 – 50,0) mg/dm3
Inductively coupled plasma optical emission spectrometry (ICP-OES) PN-EN ISO 11885:2009
70 Water, Wastewater Phenol index / volatile phenols concentration
Range (0,003 – 0,50) mg/dm3
Continuous flow analysis (CFA) with spectrophotometric detection PN-EN ISO 14402:2004 z wyłączeniem punktu 3
71 Water, Wastewater Total and free cyanide concentration
Range (0,005 – 5,0) mg/dm3
Flow injection analysis (FIA) with spectrophotometric detection PN-EN ISO 14403-1:2012
72 Water, Wastewater Combined cyanide concentration (calculated) PB-075/WA wydanie 1 z 01.06.2022r.
73 Water, Wastewater Metal concentrations
chromium (0,0010 – 1,00) mg/dm3 lead (0,0010 – 1,00) mg/dm3 copper (0,0010 – 1,00) mg/dm3 cadmium (0,00010 – 1,00) mg/dm3 nickel (0,0010 – 1,00) mg/dm3 boron (0,011 – 10,0) mg/dm3 barium (0,0030 – 1,00) mg/dm3 selenium (0,0010 – 10,0) mg/dm3 sodium (0,050 – 900,0) mg/dm3 molybdenum (0,0010 – 1,00) mg/dm3 calcium (0,10 – 450,0) mg/dm3 zinc (0,0020 – 10,0) mg/dm3 manganese (0,0030 – 1,00) mg/dm3 arsenic (0,0010 – 10,0) mg/dm3 iron (0,020 – 10,0) mg/dm3 aluminium (0,0050 – 1,00) mg/dm3 magnesium (0,10 – 90,0) mg/dm3 potassium (0,20 – 90,0) mg/dm3
Inductively coupled plasma mass spectrometry (ICP-MS) PN-EN ISO 17294-2:2024-04
74 Water, Wastewater Anion concentrations
fluorides (0,10 – 14) mg/dm3 chlorides (0,50 – 400) mg/dm3 nitrites (0,50 – 12) mg/dm3 nitrates (0,50 – 200) mg/dm3 sulfates (0,50 – 600) mg/dm3
Ion chromatography with conductometric detection (IC-CD) PN-EN ISO 10304-1:2009+AC:2012
75 Water, Wastewater Non-ionic surfactant concentration (non-ionic surface active agents)
Range (0,200 – 12,0) mg/dm3
Spectrophotometric method PB-058/WA wydanie 4 z dnia 15.07.2019 r.
76 Water, Wastewater Concentration of volatile organic compounds
dichloromethane (0,50 – 100) μg/dm3 trichloromethane (0,50 – 100) μg/dm3 tetrachloromethane (0,50 – 100) μg/dm3 Range 1,2-dichloroetan (0,50 – 100) μg/dm3 trichloroethylene (0,50 – 100) μg/dm3 tetrachloroethylene (0,50 – 100) μg/dm3 hexachlorobutadiene (0,010 – 100) μg/dm3 benzene (0,50 – 100) μg/dm3 toluene (0,50 – 100) μg/dm3 ethylbenzene (0,50 – 100) μg/dm3 xylene (sum of isomers) (1,0 – 100) μg/dm3 1,2,3-trichlorobenzene (0,010 – 100) μg/dm3 1,2,4-trichlorobenzene (0,010 – 100) μg/dm3 1,3,5-trichlorobenzene (0,010 – 100) μg/dm3 naphthalene (0,10 – 100) μg/dm3
Gas chromatography with purge and trap technique (Purge&Trap) and mass spectrometry detection (P&T GC-MS) PN-EN ISO 15680:2008
77 Water, Wastewater Polychlorinated biphenyls (PCB) concentration
PCB 28 (0,010 – 0,050) μg/dm3 PCB 52 (0,010 – 0,050) μg/dm3 PCB 101 (0,010 – 0,050) μg/dm3 PCB 118 (0,010 – 0,050) μg/dm3 PCB 138 (0,010 – 0,050) μg/dm3 PCB 153 (0,010 – 0,050) μg/dm3 PCB 180 (0,010 – 0,050) μg/dm3 PCB 194 (0,010 – 0,050) μg/dm3
Gas chromatography with electron capture detection (GC-ECD) PN-EN ISO 6468:2002
78 Water, Wastewater Chlorobenzene concentration
Range 1,2,3-trichlorobenzen Range (0,002 – 0,100) μg/dm3 1,2,4-trichlorobenzene (0,002 – 0,100) μg/dm3 1,3,5-trichlorobenzene (0,002 – 0,100) μg/dm3 pentachlorobenzene (0,002 – 0,050) μg/dm3 hexachlorobenzene (0,002 – 0,050) μg/dm3
Gas chromatography with electron capture detection (GC-ECD) PN-EN ISO 6468:2002
79 Water, Wastewater Pesticide concentration
hexachlorocyclohexane (sum of α,β,γ,δ isomers) Range (0,002 – 0,050) μg/dm3 aldrin (0,002 – 0,050) μg/dm3 dieldrin (0,002 – 0,050) μg/dm3 endrin (0,002 – 0,050) μg/dm3 isodrin (0,002 – 0,050) μg/dm3 α-endosulfan (0,002 – 0,050) μg/dm3 β-endosulfan (0,002 – 0,050) μg/dm3 p,p-DDE (0,002 – 0,050) μg/dm3 p,p-DDD (0,002 – 0,050) μg/dm3 p,p-DDT (0,002 – 0,050) μg/dm3 o,p-DDT (0,002 – 0,050) μg/dm3 alachlor (0,005 – 0,050) μg/dm3 trifluralin (0,002 – 0,050) μg/dm3 chlorfenvinphos (0,005 – 0,050) μg/dm3 chlorpyrifos-ethyl (0,002 – 0,050) μg/dm3
Gas chromatography with electron capture detection (GC-ECD) PN-EN ISO 6468:2002
80 Water, Wastewater Chloride concentration
Range (5,00 – 1000) mg/dm3
Titrimetric method PN-ISO 9297:1994
81 Water Mercury concentration
Range (15,0 – 500) ng/dm3
Atomic fluorescence spectrometry (AFS) PN-EN ISO 17852:2009
82 Water Hexavalent chromium concentration
Range (0,0050 – 1,00) mg/dm3
Inductively coupled plasma mass spectrometry (ICP-MS) PB-062/WA wydanie 2 z dnia 15.07.2019 r.
83 Water Phosphate concentration
Range (0,06 – 14,0) mg/dm3
Spectrophotometric method PN-EN ISO 6878:2006+Ap1:2010+Ap2:2010
84 Water Orthophosphate concentration
Range (0,10 – 14) mg/dm3
Ion chromatography with conductometric detection (IC-CD) PN-EN ISO 10304-1:2009+AC:2012
85 Wastewater Mercury concentration
Range (15,0 – 1000) ng/dm3
Atomic fluorescence spectrometry (AFS) PN-EN ISO 17852:2009
86 Sewage sludge Presence and count of viable eggs of intestinal parasites Ascaris sp.,Toxocara sp., Trichuris sp.,
Range od 20 jaj/kg
Flotation method, microscopic PB-09/CLB wydanie 1 z dnia 30.05.2022r.
87 Sewage sludge Metal content
chromium (1,5 – 600) mg/kg lead (0,90 – 1200) mg/kg copper (1,2 – 800) mg/kg cadmium (0,25 – 1000) mg/kg nickel (0,90 – 600) mg/kg zinc (9,0 – 2200) mg/kg magnesium (20,0 – 23 000) mg/kg calcium (150 – 110 000) mg/kg
Inductively coupled plasma mass spectrometry (ICP-MS) PN-EN 13346:2002
88 Sewage sludge Kjeldahl nitrogen content
Range (0,10 – 10,0) % Range (1,0 – 100) g/kg
Titrimetric method PN-EN 13342:2002
89 Sewage sludge Ammonium nitrogen content
Range (0,10 – 5,00) % Range (1,00 – 50,0) g/kg
Titrimetric method PB-068/WA wydanie 2 z dnia 15.07.2019 r.
90 Sewage sludge Dry residue / water content
Range (0,1 – 99,9) %
Gravimetric method PN-EN 12880:2004
91 Sewage sludge Total phosphorus content
Range (0,3 – 6,0) % Range (3,0 – 60) g/kg
Spectrophotometric method PN-EN 16174:2012 | PN-EN ISO 6878:2006 +Ap1:2010+Ap2:2010 pkt. 7
92 Sewage sludge Total phosphorus content
Range (0,3 – 8,0) % Range (3,0 – 80) g/kg
Inductively coupled plasma mass spectrometry (ICP-MS) PN-EN 16171:2017-02
93 Soil Metal content
arsenic (2 – 4000) mg/kg barium (3,0 – 400) mg/kg chromium (1,5 – 400) mg/kg zinc (9,0 – 4000) mg/kg cadmium (0,10 – 400) mg/kg copper (0,90 – 400) mg/kg molybdenum (0,50 – 400) mg/kg lead (0,90 – 400) mg/kg nickel (0,90 – 400) mg/kg cobalt (0,2 – 500 ) mg/kg tin (1,5 – 500 ) mg/kg
Inductively coupled plasma mass spectrometry (ICP-MS) PB-059/WA wydanie 4 z dnia 15.07.2019 r.
94 Soil Total organic carbon (TOC) content
Range (4 000 – 400 000) mg/kg Range (0,400 – 40,0) %
Infrared spectrometry method (IR) PN-EN 10694:2002 z wyłączeniem punktu 8.2.1
95 Soil Petrol content (C6-C12 hydrocarbons) / sum of C6-C12 hydrocarbons, components of the petrol fraction
Range (1,0 – 500) mg/kg
Gas chromatography with purge and trap technique (Purge&Trap) and mass spectrometry detection (P&T GC-MS) PB-067/WA wydanie 3 z 01.07.2023
96 Soil Dry matter content / water content
Range (0,1 – 99,9) %
Gravimetric method PN-ISO 11465:1999
97 Soil pH - in H2O
Range 3,0 – 10,0 Range 3,0 – 10,0
Potentiometric method pH - in KCl; Potentiometric method PN-EN ISO 10390:2022-09
98 Soil, Sewage sludge Mercury content
Range (0,040 – 6,00) mg/kg
Atomic absorption spectrometry with amalgamation technique PB-026/WA wydanie 7 z dnia 15.07.2019 r.
99 General environment: - waste gas samples Metal content in dust
arsenic (0,10 – 140) μg/próbkę cadmium (0,10 – 130) μg/próbkę chromium (0,60 – 250) μg/próbkę cobalt (0,20 – 25) μg/próbkę copper (4,0 – 500) μg/próbkę manganese (0,70 – 300) μg/próbkę nickel (1,2 – 70) μg/próbkę lead (0,15 – 2300) μg/próbkę thallium (0,10 – 14) μg/próbkę vanadium (0,10 – 25) μg/próbkę iron (40 – 6000) μg/próbkę zinc (17 – 8000) μg/próbkę
Inductively coupled plasma mass spectrometry (ICP-MS) PN-EN 14385:2005
100 Surface water Chlorophyll a concentration
Range (1,1 – 300) μg/dm3
Spectrophotometric method PN-ISO 10260:2002
101 Water, Wastewater Permanganate index
Range (1,3 – 200) mg/dm3 O2
Titrimetric method PN-EN ISO 8467:2001
102 Water, Wastewater Chloride concentration
Range (5,00 – 2000) mg/dm3
Titrimetric method PN-ISO 9297:1994
103 Water, Wastewater Sulfate concentration
Range (10,0 – 5000) mg/dm3
Gravimetric method PN-ISO 9280:2002
104 Water, Wastewater Ammonium nitrogen concentration
Range (0,05 – 100) mg/dm3
Spectrophotometric method PN-ISO 7150-1:2002
105 Water, Wastewater Nitrate nitrogen concentration
Range (0,04 – 100) mg/dm3
Spectrophotometric method PN-82/C-04576/08
106 Water, Wastewater Kjeldahl nitrogen concentration
Range (0,50 – 300) mg/dm3
Titrimetric method PN-EN 25663:2001
107 Water, Wastewater Total nitrogen concentration (calculated) PB-049/WA wydanie 3 z dnia 15.07.2019 r.
108 Water, Wastewater Total dissolved solids (TDS)
Range (20,0 – 2000) mg/dm3
Gravimetric method PN-EN 15216:2022-03
109 Water, Wastewater Total hardness (calculated) PB-060/WA wydanie 2 z dnia 15.07.2019 r.
110 Water, Wastewater Biochemical oxygen demand
BOD5 Range (1,0 – 6000) mg/dm3 O2
Electrochemical method PN-EN ISO 5815-1:2019-12
111 Water, Wastewater Biochemical oxygen demand
BOD5 Range (0,8 – 6,0) mg/dm3 O2
Electrochemical method PN-EN 1899-2:2002
112 Water, Wastewater Total suspended solids (TSS)
Range (5,0 – 5000) mg/dm3
Gravimetric method PN-EN 872:2007+Ap1:2007
113 Water, Wastewater Nitrite nitrogen concentration
Range (0,005 – 100) mg/dm3
Spectrophotometric method PN-EN 26777:1999
114 Water, Wastewater Orthophosphate concentration
Range (0,050 – 100) mg/dm3 P
Spectrophotometric method PN-EN ISO 6878:2006+Ap1:2010+Ap2:2010 pkt.4
115 Water, Wastewater Total phosphorus concentration
Range (0,050 – 100) mg/dm3
Spectrophotometric method PN-EN ISO 6878:2006 +Ap1:2010+Ap2:2010 pkt. 7
116 Water, Wastewater Total organic carbon concentration
Range (1,0 – 1000) mg/dm3
Spectrometry method in the infrared range (IR) PN-EN 1484:1999
117 Water, Wastewater Chemical oxygen demand
COD-Cr Range (10,0 – 1000) mg/dm3 O2
Spectrophotometric method PN-ISO 15705:2005
118 Water, Wastewater Pesticide concentration
aldrin (0,003 – 0,03) μg/dm3 dieldrin (0,003 – 0,03) μg/dm3 endrin (0,003 – 0,03) μg/dm3 isodrin (0,003 – 0,03) μg/dm3 p,p’-DDE (0,003 – 0,03) μg/dm3 p,p’-DDD (0,003 – 0,03) μg/dm3 p,p’-DDT (0,003 – 0,03) μg/dm3 o,p’-DDT (0,003 – 0,03) μg/dm3 DDT - total Range (0,003 – 0,03) μg/dm3 1,2,3-trichlorobenzene (0,004 – 0,04) μg/dm3 1,2,4-trichlorobenzene (0,004 – 0,04) μg/dm3 1,3,5-trichlorobenzene (0,004 – 0,04) μg/dm3 TCB - sum (0,004 – 0,04) μg/dm3 pentachlorobenzene (0,002 – 0,02) μg/dm3 hexachlorobenzene (0,002 – 0,02) μg/dm3 α-HCH (0,003 – 0,03) μg/dm3 β-HCH (0,003 – 0,03) μg/dm3 γ-HCH (0,003 – 0,03) μg/dm3 δ-HCH (0,003 – 0,03) μg/dm3 HCH - sum (0,003 – 0,03) μg/dm3 α – endosulfan (0,0015 – 0,015) μg/dm3 β – endosulfan (0,0015 – 0,015) μg/dm3 endosulfan – sum (0,0015 – 0,015) μg/dm3 pesticides - total (total DDT and γ-HCH) (0,003 – 0,03) μg/dm3
Gas chromatography with electron capture detection (GC-ECD) PN-EN ISO 6468:2002
119 Water, Wastewater Anion concentrations
chlorides (0,10 – 200) mg/dm3 nitrites (0,010 – 16 ) mg/dm3 nitrates (0,10 – 86) mg/dm3 orthophosphates (0,061 – 5,0) mg/dm3 sulfates (0,10 – 200) mg/dm3 fluorides (0,010 – 0,50) mg/dm3
Ion chromatography with conductometric detection (IC-CD) PN-EN ISO 10304-1:2009+AC:2012
120 Water, Wastewater Concentration of substances extractable with petroleum ether
Range (1,0 – 50) mg/dm3
Gravimetric method PN-86/C-04573/01
121 Water, Wastewater Cation concentrations:
ammonium nitrogen (0,050 – 3,0) mg/dm3 calcium (0,50 – 80) mg/dm3 magnesium (0,50 – 40) mg/dm3
Ion chromatography with conductometric detection (IC-CD) PN-EN ISO 14911:2002
122 Water, Wastewater Mineral oil index
Range (0,06 – 600) mg/dm3
Gas chromatography with flame ionization detection (GC-FID) PN-EN ISO 9377-2:2003
123 Sewage sludge Presence and count of viable eggs of intestinal parasites Ascaris sp.,Toxocara sp., Trichuris sp.,
Range od 20 jaj/kg
Flotation method, microscopic PB-09/CLB wydanie 1 z dnia 30.05.2022r.
124 Sewage sludge Dry residue / water content
Range (0,1 – 99,9) %
Gravimetric method PN-EN 12880:2004
125 Sewage sludge Loss on ignition / organic matter content
Range (0,1 – 80,0) %
Gravimetric method PN-EN 15935:2022-01
126 Sewage sludge pH - in H2O
Range 2,0 – 12,0
Potentiometric method PN-EN ISO 10390:2022-09
127 Waste code: 20 03 03 19 13 03 17 05 03 Mineral oil content (C10-C40 hydrocarbons)
Range (50 – 10 000) mg/kg
Gas chromatography with flame ionization detection (GC-FID) PN-EN 14039:2008
128 Soil Mineral oil content (C12-C35 hydrocarbons) / sum of C12 – C35 hydrocarbons, components of the oil fraction
Range (50 – 10 000) mg/kg
Gas chromatography with flame ionization detection (GC-FID) PN-EN ISO 16703:2011
129 Soil Dry matter content / water content
Range (0,1 – 99,9)%
Gravimetric method PN-ISO 11465:1999
130 Soil Pesticides content aldrin (0,2 – 120) μg/kg dieldrin (0,2 – 400) μg/kg endrin (0,2 – 400) μg/kg p,p’-DDE (0,2 – 120) μg/kg p,p’-DDD (0,2 – 120) μg/kg p,p’-DDT (0,2 – 250) μg/kg o,p’-DDT (0,2 – 250) μg/kg, total DDT (0,2 – 250) μg/kg α-HCH (0,2 – 400) μg/kg β-HCH (0,2 – 300) μg/kg γ-HCH (0,2 – 300) μg/kg Gas chromatography with electron capture detection (GC-ECD) PN-ISO 10382:2007
131 Soil pH
Range 2,0 – 12,0
Potentiometric method PN-EN ISO 10390:2022-09
132 Water Total calcium and magnesium content ( total hardness)
Range (5,0 – 1000) mg/dm3 CaCO3
Titrimetric method PN-ISO 6059:1999
133 Water Total organic carbon concentration
Range (0,50 – 1000) mg/dm3
Spectrometry method in the infrared range (IR) PN-EN 1484:1999
134 Water Chlorophyll a concentration
Range (1,1 – 350) μg/dm3
Spectrophotometric method PN-ISO 10260:2002
135 Water, Wastewater Ammonium nitrogen concentration
Range (0,05 – 200) mg/dm3
Spectrophotometric method PN-ISO 7150-1:2002
136 Water, Wastewater Nitrate nitrogen concentration
Range (0,10 – 200) mg/dm3 Nitrate concentration (0,44 – 886) mg/dm3
Spectrophotometric method PN-82/C-04576/08
137 Water, Wastewater Nitrite nitrogen concentration
Range (0,0024 – 10) mg/dm3 Nitrite concentration (0,060 – 250) mg/dm3
Spectrophotometric method PN-EN 26777:1999
138 Water, Wastewater Kjeldahl nitrogen concentration
Range (0,20 – 1000) mg/dm3
Spectrophotometric method PN-EN 25663:2001
139 Water, Wastewater Total nitrogen concentration (calculated) PB-049/WA wydanie 3 z dnia 15.07.2019 r.
140 Water, Wastewater Chloride concentration
Range (5,0 – 2000) mg/dm3
Titrimetric method PN-ISO 9297:1994
141 Water, Wastewater Permanganate index
Range (0,85 – 200) mg/dm3 O2
Titrimetric method PN-EN ISO 8467:2001
142 Water, Wastewater Dissolved phosphate concentration
Range (0,025 – 240) mg/dm3
Spectrophotometric method PN-EN ISO 6878:2006+Ap1:2010+ Ap2:2010 p. 4
143 Water, Wastewater Total phosphorus concentration
Range (0,010 – 80) mg/dm3
Spectrophotometric method PN-EN ISO 6878:2006+Ap1:2010+ Ap2:2010 p. 4, p. 7, p. 8
144 Water, Wastewater Total dissolved solids (TDS)
Range (50,0 – 10000) mg/dm3
Gravimetric method PN-EN 15216:2022-03
145 Water, Wastewater Total suspended solids (TSS)
Range (5,0 – 1000) mg/dm3
Gravimetric method PN-EN 872:2007+Ap1:2007
146 Water, Wastewater Sulfate concentration
Range (5,0 – 2000) mg/dm3
Gravimetric method PN-ISO 9280:2002
147 Water, Wastewater Hexavalent chromium concentration
Range (0,0080 – 100) mg/dm3
Spectrophotometric method PN-77/C-04604.08
148 Water, Wastewater Biochemical oxygen demand
BOD5 Range (1,0 – 6,0) mg/dm3 O2
Electrochemical method PN-EN 1899-2:2002
149 Water, Wastewater Biochemical oxygen demand
BOD5 Range (1,0 – 6000) mg/dm3 O2
Electrochemical method PN-EN ISO 5815-1:2019-12
150 Water, Wastewater Anionic surfactant concentration
Range (0,10 – 50) mg/dm3
Spectrophotometric method PN-EN 903:2002
151 Water, Wastewater Concentration of substances extractable with petroleum ether
Range (1,0 – 200) mg/dm3
Gravimetric method PN-86/C-04573.01
152 Water, Wastewater Anion concentrations:
chlorides (0,50 – 70,0) mg/dm3 nitrites (0,50 – 50,0) mg/dm3 nitrates (0,50 – 70,0) mg/dm3 orthophosphates (0,50 – 70,0) mg/dm3 sulfates (0,50 – 70,0) mg/dm3 fluorides (0,10 – 14) mg/dm3
Ion chromatography with conductometric detection (IC-CD) PN-EN ISO 10304-1:2009+AC:2012
153 Water, Wastewater Ammonium nitrogen concentration
Range (0,080 – 4,0) mg/dm3
Ion chromatography with conductometric detection (IC-CD) PN-EN ISO 14911:2002
154 Water, Wastewater Chemical oxygen demand
COD-Cr Range (10,0 – 5000) mg/dm3 O2
Spectrophotometric method PN-ISO 15705:2005
155 Water, Wastewater Concentration of polycyclic aromatic hydrocarbons
naphthalene (0,0020 – 100) μg/dm3 anthracene (0,0010 – 100) μg/dm3 fluoranthene (0,0020 – 100) μg/dm3 benzo(b)fluoranthene Range (0,0010 – 100) μg/dm3 benzo(k)fluoranthene (0,0005 – 50) μg/dm3 benzo(a)pyrene (0,0010 – 100) μg/dm3 dibenzo(ah)anthracene (0,001 – 100) μg/dm3 benzo(ghi)perylene (0,0014 – 100) μg/dm3 indeno (1,2,3-cd)piren (0,001 – 100) μg/dm3
High-performance liquid chromatography with fluorescence detection (HPLC-FLD) PB-072/WA wydanie 1 z dnia 28.09.2020 r.
156 Water, Wastewater Aromatic hydrocarbons (BTEX) concentration
benzene (1,5 – 10 000) μg/dm3 toluene (1,5 – 10 000) μg/dm3 ethylbenzene (1,5 – 10 000) μg/dm3 mp-xylene (1,5 – 10 000) μg/dm3 o-xylene (1,5 – 10 000) μg/dm3 styrene (1,5 – 10 000) μg/dm3
Headspace gas chromatography with flame ionization detection (HS-GC-FID) PN-ISO 11423-1:2002
157 Water, Wastewater Sum of BTEX (calculated) PN-ISO 11423-1:2002
158 Soil Aromatic hydrocarbons (BTEX) concentration
benzene (0,075 – 200) mg/kg toluene (0,075 – 200) mg/kg ethylbenzene (0,075 – 200) mg/kg mp-xylene (0,075 – 200) mg/kg o-xylene (0,075 – 200) mg/kg styrene (0,075 – 200) mg/kg
Headspace gas chromatography with flame ionization detection (HS-GC-FID) PN-EN ISO 22155:2016-07
159 Soil Sum of BTEX (calculated) PN-EN ISO 22155:2016-07
160 Soil Dry matter content / water content
Range (0,1 – 99,9) %
Gravimetric method PN-ISO 11465:1999
161 Soil pH
Range 3,0 – 11,0
Potentiometric method PN-EN ISO 10390:2022-09
162 Soil Concentration of polycyclic aromatic hydrocarbons
naphthalene (0,0010 – 100) mg/kg phenanthrene (0,0010 – 100) mg/kg anthracene (0,0010 – 100) mg/kg fluoranthene (0,0010 – 100) mg/kg benzo(a)anthracene Range (0,0010 – 100) mg/kg chrysene (0,0010 – 100) mg/kg benzo(a)fluoranthene (0,0010 – 100) mg/kg benzo(a)pyrene (0,0010 – 100) mg/kg benzo(ghi)perylene (0,0010 – 100) mg/kg benzo(b)fluoranthene (0,0010 – 25) mg/kg benzo(k)fluoranthene (0,00050 – 25) mg/kg dibenzo(ah)anthracene (0,0010 – 25) mg/kg indeno (1,2,3-cd)piren (0,0010 – 25) mg/kg
High-performance liquid chromatography with fluorescence detection (HPLC-FLD) PB-072/WA wydanie 1 z dnia 28.09.2020 r.
163 Wastewater Presence and count of viable eggs of intestinal parasites Ascaris sp.,Toxocara sp., Trichuris sp.,
Range od 1 jaja/ dm3
Flotation method, microscopic PB-073/WA wydanie 2 z dnia 30.05.2022r.
164 Sewage sludge Presence and count of viable eggs of intestinal parasites Ascaris sp.,Toxocara sp., Trichuris sp.,
Range od 20 jaj/ kg
Flotation method, microscopic PB-09/CLB wydanie 1 z dnia 30.05.2022r.
165 Sewage sludge Dry residue / water content/dry matter
Range (0,1 – 99,9) %
Gravimetric method PN-EN 12880:2004
166 Sewage sludge pH
Range 3,0 – 11,0
Potentiometric method PN-EN ISO 10390:2022-09
167 Sewage sludge Loss on ignition / organic matter
Range (10 – 90) %
Gravimetric method PN-EN 15935:2022-01
168 Waste gases Concentration / content of aromatic hydrocarbons
benzene (0,50 – 20000) μg in the sample Range (0,0333 – 1333) mg/m3 toluene (0,50 – 20000) μg per sample (0,0333 – 1333) mg/m3 ethylbenzene (0,50 – 20000) μg in sample (0,0333 – 1333) mg/m3 xylene (0,50 – 20000) μg in sample (0,0333 – 1333) mg/m3 ethyl acetate (1,0 – 20000) μg in sample (0,0667 – 1333) mg/m3 butyl acetate (1,0 – 20000) μg in sample (0,0667 – 1333) mg/m3 styrene (0,50 – 20000) μg per sample (0,0333 – 1333) mg/m3 acetone (5,0 – 20000) μg in the sample (0,333 – 1333) mg/m3
Gas chromatography with flame ionization detection (GC-FID) PN-EN 13649:2005
169 Waste gases Concentration / content of aliphatic hydrocarbons (C6-C14)
hexane (1,0 – 20000) μg in sample Range (0,0667 – 1333) mg/m3 heptane, octane, nonane, decane, undecane, dodecane, tridecane, tetradecane (0,50 – 20000) μg in sample (0,0333 – 1333) mg/m3
Gas chromatography with flame ionization detection (GC-FID) PN-EN 13649:2005

Reference standards (94)

ISO 13320:2020
PB-026/WA wydanie 7 z dnia 15.07.2019 r.
PB-049/WA wydanie 3 z dnia 15.07.2019 r.
PB-058/WA wydanie 4 z dnia 15.07.2019 r.
PB-059/WA wydanie 4 z dnia 15.07.2019 r.
PB-060/WA wydanie 2 z dnia 15.07.2019 r.
PB-062/WA wydanie 2 z dnia 15.07.2019 r.
PB-067/WA wydanie 3 z 01.07.2023
PB-068/WA wydanie 2 z dnia 15.07.2019 r.
PB-072/WA wydanie 1 z dnia 28.09.2020 r.
PB-073/WA wydanie 2 z dnia 30.05.2022r.
PB-075/WA wydanie 1 z 01.06.2022r.
PB-09/CLB wydanie 1 z dnia 30.05.2022r.
PB-11/CLB wydanie 1 z dnia 25.09.2023r.
PN-77/C-04584
PN-77/C-04604.08
PN-82/C-04576/08
PN-86/C-04573.01
PN-86/C-04573/01
PN-EN 10694:2002 z wyłączeniem punktu 8.2.1
PN-EN 12619:2013
PN-EN 12880:2004
PN-EN 13284-1:2018-02
PN-EN 13342:2002
PN-EN 13346:2002
PN-EN 13649:2005
PN-EN 14039:2008
PN-EN 14385:2005
PN-EN 14789:2017-04
PN-EN 14790:2017-04
PN-EN 14792:2017-04
PN-EN 1484:1999
PN-EN 15058:2017-04
PN-EN 15216:2022-03
PN-EN 15935:2022-01
PN-EN 16171:2017-02
PN-EN 16174:2012
PN-EN 1899-2:2002
PN-EN 25663:2001
PN-EN 26777:1999
PN-EN 27888:1999
PN-EN 872:2007+Ap1:2007
PN-EN 903:2002
PN-EN ISO 10304-1:2009+AC:2012
PN-EN ISO 10390:2022-09
PN-EN ISO 10523:2012
PN-EN ISO 11732:2007 z wyłączeniem punktu 3
PN-EN ISO 11885:2009
PN-EN ISO 13395:2001
PN-EN ISO 14402:2004 z wyłączeniem punktu 3
PN-EN ISO 14403-1:2012
PN-EN ISO 14911:2002
PN-EN ISO 15680:2008
PN-EN ISO 16703:2011
PN-EN ISO 16911-1:2013-07 CEN/TR 17078:2017-03
PN-EN ISO 17294-2:2024-04
PN-EN ISO 17852:2009
PN-EN ISO 22155:2016-07
PN-EN ISO 5667-13:2011
PN-EN ISO 5667-6:2016-12 z wył. pkt 7.5, 7.6
PN-EN ISO 5814:2013
PN-EN ISO 5815-1:2019-12
PN-EN ISO 6468:2002
PN-EN ISO 6878:2006 +Ap1:2010+Ap2:2010
PN-EN ISO 6878:2006 +Ap1:2010+Ap2:2010 pkt. 7
PN-EN ISO 6878:2006+Ap1:2010+ Ap2:2010 p. 4
PN-EN ISO 6878:2006+Ap1:2010+ Ap2:2010 p. 4, p. 7, p. 8
PN-EN ISO 6878:2006+Ap1:2010+Ap2:2010
PN-EN ISO 6878:2006+Ap1:2010+Ap2:2010 pkt.4
PN-EN ISO 8467:2001
PN-EN ISO 9377-2:2003
PN-ISO 10260:2002
PN-ISO 10381-4:2007
PN-ISO 10381-5:2009
PN-ISO 10382:2007
PN-ISO 10396:2001
PN-ISO 11423-1:2002
PN-ISO 11465:1999
PN-ISO 15705:2005
PN-ISO 5664:2002
PN-ISO 5667-10:2021-11
PN-ISO 5667-11:2017-10
PN-ISO 6059:1999
PN-ISO 7150-1:2002
PN-ISO 9280:2002
PN-ISO 9297:1994
PN-Z-04008-4:1999
PN-Z-04030-7:1994
Punkt 3 załącznika do Rozporządzenia Ministra Klimatu dnia 17.02.2020 r. (Dz.U. 2022 poz. 2630)
Załącznik do Rozporządzenia Ministra Klimatu z dnia 17.02.2020 r. (Dz.U. 2022 poz. 2630)
Załącznik nr 2 do Rozporządzenia Ministra Środowiska z dnia 16.06.2011 r. (Dz. U. 2011 nr 140, poz.824) z wyłączeniem punktu H
Załącznik nr 3 do Rozporządzenia Ministra Środowiska z dnia 16.06.2011 r. (Dz. U. 2011 nr 140 poz. 824 i nr 288, poz. 1697) z wyłączeniem punktu H
Załącznik nr 7 do Rozporządzenia Ministra Klimatu i Środowiska z dnia 07.09.2021 r. (t. j. Dz.U. z 2023 r., poz. 1706) z wyłączeniem punktu F
Załącznik nr 8 do Rozporządzenia Ministra Klimatu i Środowiska z dnia 07.09.2021 r. (t. j. Dz.U. z 2023 r., poz. 1706)